The English team will have Edouard Mendy, Antonio Rudiger, Andreas Christensen, Jorginho, Thiago Silva, N'Golo Kante, Timo Werner, Mason Mount, Ben Chilwell, Cesar Aspilicueta and Kai Havertz on the field from the first minutes.
The guests will feature the following line-up: Thibaut Courtois, Eder Militao, Nacho Fernandez, Sergio Ramos, Ferlan Mendy, Casemiro, Luka Modric, Toni Kroos, Junior Vinicius, Eden Hazard and Karim Benzema.
The meeting will take place in London at Stamford Bridge Stadium.
The beginning is at 22:00 Moscow time.
In the first game in Madrid, the teams did not reveal the winner - 1: 1.
Earlier, Marez's double brought Manchester City a victory over PSG in the second leg of the Champions League semi-finals.